基金项目：化学工程国家重点联合实验室浙江大学聚合反应工程实验室开放基金资助项目(
KF 9904)。
作者简介：李晓，男， 30岁，博士，副教授。已发表论文近
20篇。
作者单位：李晓（福州大学化学工程系，福建福州 350002）
张卫英（福州大学化学工程系，福建福州 350002）
袁惠根（浙江大学高分子科学与工程研究所，浙江杭州
310027）
参考文献：
［1］Sharma M K, Shah D O. Introduction to macro－ and
microemulsions[A].Shah D O.Macro－ and microemulsions, theory and application[C].
Washington D C:ACS,1985. 1
［2］Bourrel M, Schechter R S.Microemulsions and related systems,formulation,solvency
and physical properties[M]. New York: Marcel Dekker Inc, 1988
［3］Shinoda K,Kunicda H. Conditions to produce so－ called microemulsions: Factors to
increase the mutual solubility of oil and water by solubilizer[J]. J Colloid Interface
Sci, 1973,42:381
［4］Schwuger M J, Stickdom K. Microemulsions in technical processes[J]. Chem Rev, 1995,
95: 849
［5］Stoffer J O, Bone T. Polymerization in water－ in－ oil microemulsion
systems.I[J]. J Polym Sci, Polym Chem Ed, 1980, 18:2 641
［6］Leong Y S, Candau F. Inverse microemulsion polymerization[J]. J Phys Chem, 1982,
86(12): 2 269
［7］钱人元 , 吴立衡.柔性链高聚物的单分子链玻璃体和单晶 [J].
化学进展 , 1996, 8 (3):177
［8］Atik S S, Thomas J K. Polymerized microemulsions[J]. J Am Chem Soc, 1981,103:4 279
［9］Johnson P L, Gulari E. Characteristics of microemulsion polymerized styrene with
water－ soluble versus oil－ soluble initiators[J]. J Polym Sci,Polym Chem Ed, 1984,22:3
967
［10］Kuo P L, Turro N J, Tseng C M. Photoinitiated polymerization of styrene in
microemulsions[J]. Macromolecules,1987,20:1 216
［11］Guo J S, El－ Aasser M S, Vanderhoff J W. Microemulsion polymerization of
styrene[J]. J Polym Sci,Polym Chem Ed,1989,27:691
［12］Feng L, Ng K Y S. In situ kinetic studies of microemulsion polymerization of
styrene and methyl methacrylate by Raman spectroscopy[J].Macromolecules,1990,23:1 048
［13］Gan L M, Chew C H, Lye I, et al. Microemulsion polymerization of styrene[J]. Polym
Bull, 1991, 25: 193
［14］Ferrick M R, Murtagh J, Thomas J K. Synthesis and characterization of polystyrene
latex particles[J]. Macromolecules,1989,22:1 515
［15］Puig J E, Luna H P, Gonzalez M P, et al. Comparison of oil－ soluble and water－
soluble initiation of styrene polymerization in a three－ companent microemulsion[J].
Colloid Polym Sci, 1993, 271: 114
［16］Gan L M, Chew C H, Lee K C. Formation of polystyrene nanoparticles in ternary
cationic microemusions[J]. Polymer, 1994, 35(12):2 659
［17］Fitch R M. Polymer Colloids[M]. New York: Plenum Press, 1973. 73
［18］Jayakrishnan A, Shah D O. Polymerization of oil－ in－ water microemulsions:
Polymerization of styrene and methyl methacrylate[J]. J Polym Chem,Polym Lett Ed,
1984,22:31
［19］Antonietti M, Bremser W, Muschenborn D, et al. Synthesis ad size control of
polystyrene latices via polymerizaton in microemulsion[J]. Macromolecules, 1991,24:6 636
［20］Ugelstad J, El－ Aasser M S, Vanderhoff J W. Emulsion polymerization: Initiation
of polymerization in monomer droplets[J]. J Polym Sci,Polym Lett Ed,1973,11:503
［21］Kuo P L, Turro N J, Tseng C M, et al. Photoinitiated polymerization of styrene in
micro－ emulsions[J]. Macromolecules, 1987, 20: 1 216
［22］Guo J S, Sudol E D, Vanderhoff J W, et al. Particle nucleation and partitioning in
styrene O/W microemulsion polymerization[J]. J Polym Sci,Polym Chem Ed, 1992, 30: 691
［23］徐相凌 ,张志成 ,张曼维 ,等 .过硫酸钾引发苯乙烯微乳液聚合
[J].高等学校化学学报 ,1997,18(9): 1 546
［24］贾世军 ,陈柳生 ,金熹高.微乳液聚合和寡链高分子凝聚态研究进展
[J]. 功能高分子学报 ,1997,10(3): 408
［25］Vanderhoff J W, Bradford E B, Tarkowski H L, et al. Polymerization and
polycondensation processes[J]. Adv Chem Ser,1962,34:32
［26］Candau F, Leong Y S, Fitch R M. Kinetic study of the polymeriztion of acrylamide
in inverse microemulsion[J]. J Polym Sci,Polym Chem Ed, 1985,23:193
［27］Barton J. Partitioned polymerization,6[J]. Makromol Chem Rapid Commun,1991, 2: 675
［28］Janigov I, Csomorov K, Stillhammerov M, et al. Differential scanning
calorimetry and thermogravimetry studies of polyacrylamide prepared by free－ radical
polymerization in inverse microemulsion and in solution[J]. Macromol Chem Phys, 1994,195:3
609
［29］张志成 ,徐相凌 ,张曼维.丙烯酰胺微乳液聚合 [J]. 高分子学报
,1994,(4):426
［30］Va kov á V, Juranicová V, Barton J. Polymerization in
inverse microemulions, 2[J]. Makromol Chem, 1991,192:989
［31］Vaková V, Juranicová V, Barton J. Polymerization in
inverse microemulions, 3[J]. Makromol Chem, 1991,192:1 339
［32］哈润华 ,侯斯健 .（2－甲基丙烯酰氧乙基）三甲基氯化铵－丙烯酰胺反相微乳液共聚合研究
[J]. 高分子学报 ,1993,(5):570
［33］Gan L M, Chew C H, Friberg S E. Polymerization of styrene in water－ alcohol－
ionic surfactant solutions[J]. J Macromol Sci Chem,1983,A19(5):739
［34］Menger F M, Tsuno T. Cross－ linked polystyrene incorporating water－ pools[J].
J Am Chem Soc,1990, 112:1 263
［35］Candau F, Leong Y S, Pouyet G, et al. Inverse microemulsion polymerization of
acrylamide: Characterization of the water－ in－ oil microemulsions and the final micro－
latexes[J]. J Colloid Interface Sci,1984,101:167
［36］Haque E, Qutubuddin S. Novel polymeric materials from microemuslions[J]. J Polym
Sci,Polym Lett Ed, 1988, 26:429
［37］Sasthav M, Cheung H M. Characterization and polymerization of middle－ phase
microemulsions in styrene/water system[J]. Langmuir, 1991, 7: 1 378
［38］Palani Raj W R, Sasthav M, Cheung H M. Microcelluar polymeric materials from
microemulsions: Control of microstructure and morphology[J]. J Appl Polym Sci,1993,47:499
［39］Gan L M, Chieng T H, Chew C H, et al. Microporous polymeric materials from
microemulsion polymerization[J]. Langmuir, 1994, 10:4 022
［40］Palani Raj W R, Sasthav M, Cheung H M. Polymerization of single－ phase
microemulsions: Dependence of polymer morphology on microemulsion structure[J]. Polymer,
1995, 36 (13): 2 637
［41］Candau F, Zekhnini Z, Durand J P. Copolymerization of water－ soluble monomers in
nonionic bicontinous microemulsion[J]. J Colloid Interface Sci,1986,114(2):398
［42］Gan L M, Chieng T H, Chew C H, et al. Microporous polymeric materials from
microemulsion polymerization[J]. Langmuir, 1994,10: 4 022
［43］Corpart J M, Candau F. Formulation and polymerization of microemulsions containing
mixture of cationic and anionic monomers[J]. Colloid Polym Sci,1993,271(11): 1 055
收稿日期：2000年1月1日
修稿日期：2000年7月5日
出版日期：2000年11月15日 |
