橡胶技术网

合成橡胶工业
CHINA SYNTHETIC RUBBER INDUSTRY
2001 Vol.24 No.1 P.46-50

橡胶技术网

EPDM/PP热塑性动态硫化胶的进展

孙亚娟  张美珍  周凯梁  吴崇刚 

摘 要:阐述了EPDM/PP共混型热塑性动态硫化胶的发展历史、制备工艺、徽观相态结构、性能、加工技术和应用领域。
关键词:三元乙丙橡胶;聚丙烯;动态硫化;热塑性弹性体;综述
分类号:TQ333.9 文献标识码:A

文章编号:1000-1255(200)01-0046-05

Development of EPDM/PP thermoplastic dynamic vulcanizates

Sun Yajuan(Institute of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029) 
Zhang Meizhen(Institute of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029) 
Zhou Kailiang(Institute of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029) 
Wu Chonggang(Institute of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029) 

AbstractThe development history, preparationtechnology, micromorphology, properties, processingtechnology and applications of EPDM/PP blendthermoplastic dynamic vulcanizates were reviewedwith 45 references.
Keywords:ethylene propylene diene monomer;polypropylene;dynamic vulcanization;thermoplasticelastomer;review

作者简介:孙亚娟,女,25岁,硬士生。
作者单位:孙亚娟(北京化工大学材料科学与工程学院,北京 100029) 
     张美珍(北京化工大学材料科学与工程学院,北京 100029) 
     周凯梁(北京化工大学材料科学与工程学院,北京 100029) 
     吴崇刚(北京化工大学材料科学与工程学院,北京 100029) 

参考文献:

[1]Choudhury N R,Bhowmick A K.Strength of thermoplastic elastomers from rubber-polyolefin blends[J].Journal of Material sScience,1990,2S (1):161~167
[2]Legge N R.热塑性弹性体的三十年进展[J].橡胶译丛,1990(6):78
[3]School R.TPE production and use in the 1990s[J].Rubber World,1990,201 (6):15
[4]Berta D A.Preparation of thermoplastic elastomers by dynamic curing of polyolefins and ethylene-propene rubber [P].U S,US 4 948 840.1989
[5]Radusch H J.Dynamic vulcanizates on the basis of polypropylene/rubber mixtures[J].Kautsch Gummi Kunstst,1990,43(9):767~769
[6]Brags V.Manufacture of thermoplastic elastomer compositions from polyolefins and rubber[P].Eur Pat Appl,EP 361 205.1990
[7]酒井忠基.反应性加工技术的现状与未来展望[J].塑料时代(日文),1990,36(2):137
[8]Radusch H J.Dynamic vulcanization of EPDM-polypropylene mixtures[J].Kautsch Gummi Kunstst,1991,44(12):1125~1128
[9]Kim M H.Preparation of thermoplastic elastomers from polyolefin-EPDM rubber blends[P].Eur Pat Appl,EP 519 691.1992
[10]Noel O F.Talc in thermoplastic elastomers[J].Rubber Chem Technol,1993,6 (1):152
[11]Fitz H G.Elastic properties of thermoplastic elastomers on the basis of dynamic vulcanized PP/EPDM blends[J].Kautsch Gummi Kunstst,1993,46(5):374~379
[12]Krulis Z.Effect ofdynamic crosslinking on mechanical properties of PP/EPDM blends[J].Collect Czech Chem Commun,1993,58(11):2 642~2 650
[13]Anderlik R.Compounding of thermoplastic elastomers using modified dynamic crosslinking steps[A].Stuttg Kunstst Kolloq[C].Heidelberg:Dr Alfred Huethig Verlng Gmdh Posffach,[C].Heidelberg:Dr Alfred Huethig Verlng Gmdh Posffach,1993.243~253
[14]Rsdusch H J.Thermoplastic elastomers based on dynamic vulcanized PP/rubber blends[A].Pr Nauk Politech Szczecin[C].Szczecin:Polipechnika Szczeeinska,1994.99~103
[15]paganelli G.Elastomeric thermoplastic blends and process for preparing them[P].U S,US 5 384 366.1994
[16]Toshio I.Selective crosslinking in polymer blends I.Novel selective crosslink systems for polypropylene/unsaturated elestomer blends[J].J Appl Polym Sci,1994,54(6):709
[17]Tung P.Modeling of the reactive compounding of polymer blends[J].Plaste Kautsch,1994,41 (2):53~59[J].Plaste Kautsch,1994,41 (2):53~59
[18]Ysmaguchi M.Rheological properties of olefinic thermoplastic elastomem [J].Nihon Reoroji Gakkaishi,1995,23 (3):125~130
[19]Marinovic T.Rheology of dynamically crosslinking alloys PP/EPDM[J].Kovine Zlitine Techmol,1995,29(1~2):282~283
[20]Dharia A N.Effects of the test parameters on the compression setof dynamically vulcanized alloys[J].Aunu Tech Conf-Soc PlastEng,1995,53 (3):4 071~4 077
[21]Kim Young-Kyo,Cho Won-Je,Ha Chang-Sik.The control ofmiscibility of PP/EPDM blends by adding ionomers and applyingdynamic vulcanization[J].Polym Eng Sci,1995,35(20):1592
[22]Hikasa T.Noubleeding thermoplastic elastomer compositionsuseful for molding and their manufacture[P].Jpn Kokai TokkyoKoho,JP 07 138 378.1995
[23]齐藤正明.橡塑共混型热塑性弹性体的用途[J].日本橡胶协会志(日文),1996,69(9):631
[24]肖汉文,黄世强,刘少波.EPDM/PP热塑性弹性体的新进展[J].特种橡胶制品,1999,20(4):23~26[J].特种橡胶制品,1999,20(4):23~26
[25]朱玉俊,徐固,赵晓温.聚烯烃系共混型动态硫化法热塑性弹性体的研制及有关性能探讨[J].特种橡胶制品,1984,5(3):9~17
[26]殷敬华.乙丙橡胶/聚丙烯热塑弹性体及制备方法[P].中国,ZL 85 1 02 222 X.1988
[27]朱玉俊.乙丙橡胶/聚烯烃热塑性弹性体及制备方法[P].中国,ZL 91109976 X.1994
[28]唐涛,应圣康,胡春圈.聚醚型TPU/NBR-40动态硫化共混型热塑性弹性体的制备与性能[J].橡胶工业,1992,39(12):743~747
[29]张中岳,乔金梁.全硫化EPDM/PP热塑性弹性体制备的优化工艺条件[J].合成橡胶工业,1992,15(4):205~207
[30]耿海萍.共混型热塑性乙丙胶的结构与性能及其工业化开发的研究[D].北京:北京化工大学,1993
[31]张祥福.TPVO热塑性弹性体流变行为的研究[J].化学世界,1995,36(11):591~595
[32]潘炯玺,叶林忠,李刚,等.动态硫化PP/EPDM热塑性弹性体性能的研究[J].橡胶工业,1997,44(5):259~261
[33]吴崇刚.反应挤出——用国产双螺杆挤出机制备低硬度EPDM/PP共混型热塑性动态硫化胶的工艺可行性及其工艺-结构-性能的研究[D].北京:北京化工大学,1998
[34]张殿荣,张兆庆,浒健,等.动态硫化聚氯乙烯/再生胶/硫化胶粉共混型热塑性弹性体的研制[J].合成橡胶工业,1998,21(2):84~87
[35]廖明义,舒文森,李建丰,等.高聚合度聚氯乙烯/SBR动态硫化共混物力学性能的研究[J].橡胶工业,1999,46(5):259~261
[36]邱方正,高乃奎,谢恒坤.动态硫化对聚烯烃热塑性弹性体力学性能的影响[J].合成橡胶工业,1999,22(4):213~215
[37]吴唯,徐种德,周达飞.交联剂对动态硫化PP/EPDM中PP晶体及EPDM形态结构的影响[J].合成橡胶工业,1999,22(4):225~229
[38]吴唯.EPDM分布形态对动态硫化PP/EPDM共混物增韧效果的影响及其机理的研究[J].橡胶工业,1999,46(6):323~329
[39]郭红革,肖建斌,刘勇智,等.配方和共混方法对EPDM/PP性能的影响[J].特种橡胶制品,1999,20(5):9~14
[40]朱玉俊.弹性体的力学改性[M].北京:科学技术出版社,1992.119
[41]Vander J P.The effect of fumed silica in RTV - 1 silicone rubbersealants[J].Rubber World,1985,192(5):32
[42]Rander C P.The application of Santoprene by blow moldingprocessing technology[J].Rubb Plast News,1985,15 (2):32
[43]Menough J.Foaming TPE[J].Rubber World,1986,195(3):12
[44]Peterson D E,Weider B K.Vacuum thermoforming of thermo-plastic vulcanizates [J].Plast Eng,1986,42(9):49
[45]Agrawal P D.A new safe thiuram[J].Rubber World,1990,102(5):20

收稿日期:2000年1月31日

修稿日期:2000年8月31日

出版日期:2001年1月15日