白炭黑的特性及其在胎面胶中的应用

宁凯军　 王小萍　 贾德民　

摘　要：介绍了白发黑的结构特点、改性方法及其对胎面胶结构和性能的影响，简述了白炭黑在轮胎中的应用。
关键词：轮胎；胎面胶；白炭黑；滚动阻力；改性；应用
分类号：TQ330.38⁺1　文献标识码：A
文章编号：1000-1255(2001)03-0182-03

Characteristics of silica and its application in tire treads

Ning Kai jun（Faculty of Materials Science and Engineering, South China University of Technology,Guangzhou 510640, China）　
Wang Xiaoping（Faculty of Materials Science and Engineering, South China University of Technology,Guangzhou 510640, China）　
Jia Demin（Faculty of Materials Science and Engineering, South China University of Technology,Guangzhou 510640, China）　

Abstract：The advance in the basic research of structure and properties of silica in rubber industry was reviewed with 18 references. The application of silica in tire tread was briefly introduced.
Keywords：tire; tire tread; silica; rolling resistance;modification; application

参考文献：

［1］Wolff S, God U,Wang M J, et al. Silica-based tread compounds [J]. European Rubber Journal, 1994, 176(1): 16
［2］Savis B. Blaclk, silica capacities increase[J]. European Rubber Journal, 1994, 176(7 ～8): 31
［3］WaddeH W H, Evans L R. Use of nonblack fillers in tire compounds[J]. Rubber Chemistry and Technology, 1996, 69(3):377
［4］David S. Niche in tire industry for silica[J]. European Rubber Journal, 1996, 178(5): 28
［5］Wolff S, G,orl U, Wang M J, et al. How does silica differ from carbon black[J]. European Rubber Journal, 1994, 176(1): 17
［6］Wang M J, Wolff S, Donnet J B. Filler-elastomer interactions:Part I. Silica surface energies and interactions with model compounds[J]. Rubber Chemistry and Technology, 1990, 64(3):559
［7］Li Yingbing, Wang M J, Zhang Tao, et aL Study on dispersion morphology of silica in rubber[J] . Rubber Chemistry and Technology, 1994, 67(4): 693
［8］Wolff S, Wang M J, Tan E H. Dynamic properties of carbonblack-filled vulcanizates and shift factors[J].Kautachukund Gummi Kunststoffe, 1995, 48(2): 82
［9］吴均海.白炭黑与偶联剂-Si 69在胎面胶中的应用尝试[J].橡胶工业,1986,30(6):18
［10］Wolff S. Silica- based tread compound: Background and performance[A]. Tyre Tech ′93 [C]. Basel, Switzerland, 1993
［11］Mandal S K, Basu D K. Reactive compounds for effective utilization of silica[J] . Rubber Chemistry and Technology, 1994,67 (4): 672
［12］Ou Yuchun, Yu Zhongzhen. Effects of alkylaion of silica ifller on rubber reinforcement[J]. Rubber Chemistry and Technology,1994, 67(5): 834
［13］Grosch K A. The rolling resistance, wear and traction properties of tread compounds[J]. Rubber Chemistry and Technology,1996,69(3):495
［14］Cochrane H, Lin C S. The influence of fumed silica properties on the processing, curing, and reinforcement properties of silicone rubber[J]. Rubber Chemistry and Technology, 1993, 66(1): 48
［15］Bomal Y, Recherches R P. Influence of specific surface area and quantity of precipitated silica on the properties of a precipitated silica filled natural rubber[J]. Rubber Chemishy and Technolo8y, 1993, 66(4): 685
［16］Rubber Research Institute of Malaysia. Developments in epoxidized natural rubber[J]. Rubber Chemistry and Technofogy,1995, 68(2): 161
［17］Abmad A, Schaefer R J. Energy saving tire with silica- rich tread[P]. U S, US 4 519 430. 1995
［18］Evans L R, Waddell W H. Ultra-high reinforcing precipitated silica for tire and rubber applications[J]. Kautachuk und Gummi Kunststoffe, 1995, 48(10): 718

收稿日期：2000年1月10日

修稿日期：2000年12月19日

出版日期：2001年5月15日