橡胶技术网

合成橡胶工业
CHINA SYNTHETIC RUBBER INDUSTRY
2002 Vol.25 No.1 P.45

 橡胶技术网

Effect of talc/BA in-situ polymerization on mechanical properties of PP-matric composites

Zhang Weixing（Department of Chemistry,Huazhong University of Science and Technology,Wuhan 430074,China）　
Xie Xiaolin（Department of Chemistry,Huazhong University of Science and Technology,Wuhan 430074,China）　
Yang Jiling（Department of Chemistry,Huazhong University of Science and Technology,Wuhan 430074,China）　
Deng Zexian （Departmemt of Manufacture Engeering,Hongkong Polytechnic University,Kowloon,Hongkong,China）　

滑石粉 /BA原位聚合对聚丙烯复合材料力学性能的影响

章卫星　 解孝林　 杨继林　 邓泽贤　

摘　要：采用滑石粉/丙烯酸丁酯(BA)原位乳液聚合,制备了表面包覆聚丙烯酸丁酯填充料,再与聚丙烯共混.结果表明,滑石粉对 BA无阻聚作用,表面包覆的聚丙烯酸丁酯(PBA)能有效地解决复合材料的界面粘接,并存在一临界 PBA包覆层厚度 .
关键词：滑石粉;丙烯酸丁酯;原位乳液聚合;聚丙烯酸丁酯;共混
CLC Number：TQ32　Document ID：B

　　Filler-reinforced polymer composites have attracted considerable attention due to their enhanced properties.However,the tensile and impact strength of these composites is weak due to the difference in surface energy between the inorganic fillers and polymer matrix.Therefore,improving the interfacial adhesion between the inorganic particles and the polymer matrix by modifying the filler surface becomes inevitable in toughening the composites.Recently,some new approaches,have been developed for particulate surface treatment to produce high performance PRPC[1,2].In this paper,the in-situ polymerization of butyl acrylate (BA) on the surface of the micro-sized talc was performed by using the batch seed emulsion polymerization.The treated talc was subsequently used to fill polypropylene(PP).It is expected that the PBA covered on the surface of talc can improve the mechanical properties of the PP-matrix composites.
　　……
Foundation Item：Supported by National Natural Science Foundation of China(50003005) and Hongkong Polytechnic University.
Author Resume：Zhang Weixing,Mphil D student. Xie Xiaolin, To whom all correspondence should be addressed.
　　　　　章卫星（华中科技大学化学系,湖北武汉,430074）　
　　　　　解孝林（华中科技大学化学系,湖北武汉,430074）　
　　　　　杨继林（华中科技大学化学系,湖北武汉,430074）　
　　　　　邓泽贤（香港理工大学制造工程系,香港九龙）　

References：

［1］Xie X L,Li B G,Pan Z R.J Mater Sci Eng,1999,17(2):632
［2］Xie X L,Li B G,Pan Z R,et al.J Appl Polym Sci,2001(80): 2 105

Manuscript Received：2001年9月3日

Published：2002年1月15日

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