Controlled homopolymerization of 2, 2, 3, 3-tetrafluoropropyl methacrylate with Schiff base complexes of cobalt(Ⅱ)

Liang Yuanyuan（Department of Chemistry and State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Nankai University, Tianjin 300071, China）　
Yang Wenying（Department of Chemistry and State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Nankai University, Tianjin 300071, China）　
Liu Xiangyi（Department of Chemistry and State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Nankai University, Tianjin 300071, China）　
Zhang Bingnan（Department of Chemistry and State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Nankai University, Tianjin 300071, China）　
Huang Jiaxian（Department of Chemistry and State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Nankai University, Tianjin 300071, China）　

Co(Ⅱ)Schiff碱配合物作用下甲基丙烯酸-2,2,3,3-四氟丙酯可控均聚

梁嫒嫒　 杨文英　 刘翔宜　 张炳楠　 黄家贤　

摘　要：以系列Co(Ⅱ)Schiff碱配合物为催化体系合成了相对分子质量可控、分布较窄的甲基丙烯酸-2,2,3,3-四氟丙酯均聚物.Co(Ⅱ)配合物的结构影响其在聚合中的催化效果.
关键词：Co(Ⅱ)Schiff碱配合物;可控均聚;甲基丙烯酸-2,2,3,3-四氟丙酯
CLC Number：TQ33　Document ID：A

References：

［1］Wang Jinshan, Matyjaszewski. J Am Chem Soc, 1995, 117(20):5 614
［2］Kato M, Kamigaito M, Sawamoto M, et al. Macromolecules, 1995,28(5): 1 721

Manuscript Received：2002年12月24日

Published：2003年5月15日