橡胶技术网

合成橡胶工业
CHINA SYNTHETIC RUBBER INDUSTRY
2007 Vol.30 No.3 P.236

橡胶技术网

澳化亚铜催化下的甲基丙烯酸甲醋(MMA)与乙烯的共聚合

国岩  袁荞龙  黄葆同 

关键词:甲基丙烯酸甲酯;乙烯;原子转移自由基聚合;溴化亚铜;催化

Copolymerization of methyl methacrylate and ethylene catalyzed with CuBr

Guo Yan (School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China)  Yuan Qiaolong(School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China)  Huang Baotong(School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China;Changchun Institute of Applied Chemistry, Chinese Academy of Science, Changchun 130022, China) 

  It has become an interesting research work to increase the surface property of the polyolefin and extend the use of the polyolefin by the copolymerization of non-polar α-olefins with polar monomers.……

作者简介:Guo Yan, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai graduate student.
作者单位:国岩(华东理工大学,材料科学与工程学院,上海,200237) 
     袁荞龙(华东理工大学,材料科学与工程学院,上海,200237) 
     黄葆同(华东理工大学,材料科学与工程学院,上海,200237;中国科学院,长春应用化学研究所,吉林,长春,130022) 

参考文献:

[1]Liu Shengsheng,Elyashiv S,Sen A.Copper-mediated controlled copolymerization of methyl acrylate with 1-alkenes under mild conditions[J].J Am Chem Soc,2001,123(50):12 738 ~ 12 739

收稿日期:2006年12月7日

出版日期:2007年5月15日

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