橡胶技术网

合成橡胶工业
CHINA SYNTHETIC RUBBER INDUSTRY
2007 Vol.30 No.3 P.237-241

橡胶技术网

醇钾和酚钾助引发剂在负离子聚合中的应用研究进展

任春晓  王玉荣  王启飞  于国柱  李杨  张春庆 

摘 要:介绍了醇钾和酚钾作为助引发剂的负离子聚合机理,综述了醇钾和酚钾作为助引发剂在负离子聚合中的应用研究进展,醇钾和酚钾主要调节了聚合物的序列结构和微观结构,引发了链转移反应,对聚合物可实现功能化.
关键词:醇钾;酚钾;助引发剂;负离子聚合;序列结构;微观结构;链转移;综述
分类号:TQ316.32+4 文献标识码:A

文章编号:1000-1255(2007)03-0237-05

Advance in application of potassium alkoxides and potassium phenoxides as promoter in anionic polymerization

Ren Chunxiao   Wang Yurong  Wang Qifei  Yu Guozhu  Li Yang  Zhang Chunqing 

基金项目:中国石油化工股份有限公司资助项目(405095).
作者简介:任春晓(1982-),男,硕士研究生.已发表论文1篇.
作者单位:任春晓(大连理工大学高分子材料系,辽宁,大连,116012) 
     王玉荣(大连理工大学高分子材料系,辽宁,大连,116012) 
     王启飞(中国石化北京燕山石油化工有限公司,研究院,北京,102500) 
     于国柱(中国石化北京燕山石油化工有限公司,研究院,北京,102500) 
     李杨(大连理工大学高分子材料系,辽宁,大连,116012) 
     张春庆(大连理工大学高分子材料系,辽宁,大连,116012) 

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收稿日期:2006年8月3日

修稿日期:2007年1月18日

出版日期:2007年5月15日