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	合成橡胶工业 CHINA SYNTHETIC RUBBER INDUSTRY 2009 Vol.32 No.3 P.251-256

二氧化硅增强双烯类非极性橡胶的研究进展

尹常杰　张秋禹　张和鹏　尹德忠　

摘　要：介绍了SiO_2增强非极性橡胶的2种方法:机械混炼法和原位改性法,分析了2种方法制备SiO_2增强橡胶的结构性能特点,指出原位改性法可以实现SiO_2粒子均匀分散且粒径大小可控,具有更好的改性效果.并对SiO_2增强橡胶的研究方向做出展望.
关键词：机械混炼法;原位改性法;二氧化硅;增强;非极性橡胶;综述;
分类号：TQ330.38 　文献标识码：A
文章编号：1000-1255(2009)03-0251-06

Progress in research of silica reinforced diene nonpolar-rubber

Yin Changjie（School of Science,Northwestern Polytechnical University,Xi'an 710072,China）　 Zhang Qiuyu（School of Science,Northwestern Polytechnical University,Xi'an 710072,China）　 Zhang Hepeng（School of Science,Northwestern Polytechnical University,Xi'an 710072,China）　 Yin Dezhong （School of Science,Northwestern Polytechnical University,Xi'an 710072,China）　

Abstract：The two process of reinforcing the non-polar rubber by silica,mechanically blending and in-situ modification were introduced with 31 references.The characteristics of structure and properties of silica reinforced rubber by the traditional mechanically blending and in-situ modification methods were analyzed.It was pointed out that the particle size of silica could be designed and controlled by in-situ modification process.Finally the study direction of SiO_2 reinforced rubber was suggested.
Keywords：mechanically mixing process;in-situ modification process;silica;reinforcement;non-polar rubber;review

作者简介：尹常杰(1985-),男,硕士研究生.已发表论文1篇.
作者单位：尹常杰（西北工业大学,理学院,陕西,西安,710072）　
　　　　　张秋禹（西北工业大学,理学院,陕西,西安,710072）　
　　　　　张和鹏（西北工业大学,理学院,陕西,西安,710072）　
　　　　　尹德忠（西北工业大学,理学院,陕西,西安,710072）　

参考文献：

[1]赵旭涛,刘大华.合成橡胶工业手册[M].第二版.北京:化学工业出版社,2006:200-206.
[2]Kautsch U G,Kunstst G.Investigation concerning the reaction silica/organosilane and organosilane[J].Cheric Org,1998,51(7):525-533.
[3]Gorl U,Munzenberg J,Luginsland D,et al.Investigations on the reaction siliea/organosilane and organosilane/polymer(part 4):Studies on the chemistry of the silane-sulfur chain[J].Catinist,1999,52(9):588-598.
[4]钱燕超.(1)纳米二氧化硅(SiO2)在丁苯橡胶(SBR)基体中的分散和聚集研究;(2)溴化苯酚树脂对EPDM胶料硫化特征的影响[D].北京:北京化工大学,2006.
[5]肖建斌,刘锦春,张峰,等.白炭黑/荆补强橡胶的性能研究[J].轮胎工业,2005,2(25):71-74.
[6]Pe'rez L,Giraldo L F,Lo'pez B L,et al.Reinforcing of elastomers with mesoporous silica[J].Maeromol Symp,2006,245/6(1):628-640.
[7]林桂,吴友平,钱燕超,等.纳米SiO2填充聚二甲基硅氧烷的微观结构在热贮存中的演变动力学[J].合成橡胶工业,2006,29(6):439-444.
[8]Ren Hui,Qu Yixin,Zhao Suhe.Reinforcement of styrene-butadiene rubber with silica modified by silane coupling agents[J].Experimental and Theoretical Chemistry Study,2006,14(1):93-98.
[9]赵金义,毕雪玲,周丽玲,等.硅烷偶联剂改性白炭黑在丁苯橡胶中的应用[J].青岛科技大学学报,2004,25(2):160-162.
[10]Sae-oui P,Sirisinha C,Thepsuwan U,et al.Comparison of reinforcement efficiency between Si-69 and Si-264 in a conventional vulcanization system[J].Polymer Testing,2004,23(8):871-879.
[11]Sae-oui P,Thepsnwan U,Hatthapanit K.Effect of curing system on reinforcing efficiency of silane coupling agent[J].Polymer Testing,2003,23(4):397-403.
[12]梁诚.硅烷偶联剂在橡胶工业中应用进展[J].橡胶科技市场,2007(19):14-15.
[13]周明,宋一虎,孙晋,等.硅烷偶联剂对SSBR/O2混炼胶体系动态流变行为的影响[J].高分子学报,2007(2):153-157
[14]Sun Lin,Song Yihu,Zheng Qiang,et al.Nonlinear rheological behavior of silica filler solution-polymerized styrene butadiene rubber[J].Journal of Polymer Science (part B):Polymer Physics,2007,45(18):2594-2602.
[15]王雪飞,杨军,张立群.原位接枝改性工艺对白炭黑补强NR性能的影响[J].橡胶工业,2007,54(4):212-214.
[16]Mathew G,Huh M Y,Rhee J M,et al.Improvement of properties of silica-filled styrene-butadiene rubber composites through plasma surface modification of silica[J].Polym Adv Technol,2004,15(7):400-408.
[17]Cataldo F.Preparation of silica-based rubber compounds without the use of a silane coupling agent through the use of epoxidized natural rubber[J].Macrnmol Mater Eng,2002,287(5):348-352.
[18]段先健.溶胶-凝胶法原位生成纳米SiO2粒子增强橡胶及EPDM补强机理的初步研究[D].北京:北京化工大学,2001.
[19]Duan Xianjian,Wu Shemao,Zhong Rongdong,et al.In-situ silica reinforcing EPDM by sol-gel method[J].合成橡胶工业,2001,24(4):234.
[20]Ikeda Y,Kohjiya S.In situ formed silica particles in rubber valcanizate by the sol-gel method[J].Polymer,1997,38(17):4417-4423.
[21]Bokobzaa L,Chauvinb J P.Reinforcement of natural rubber:Use of in situ generated silicas and nanofibres of sopiolite[J].Polymer,2005,46(12):4144-4151.
[22]De D,Das A,Kumar P,et al.Reinforcing effect of silica on the properties of styrene-butadiene rubber-reclaim rubber blend system[J].Journal of Applied Polymer Science,2006,99(3):957-968.
[23]Hashim A S,Kohjiya S,Ikeda Y.Moisture cure and in-situ silica reinforcement of epoxidized natural rubber[J].Polymer International,1995,38(2):111-117.
[24]黄祖长.用原位生成的白炭黑补强NR:与炭黑补强胶料的对比[J].橡胶参考资料,2002,32(2):668-672.
[25]Ikeda Y,Kameda Y.Preparation of "green" composites by sol-gel process:In situ silica filled natural rubber[J].Journal of Sol-Gel Science and Technology,2004,31(1/3):137-142.
[26]Murakami K,lio S,lkeda Y,et al.Effect of silane-coupling agent on natural rubber filled with silica generated in situ[J].Journal of Materials Science,2003,38(7):1447-1455.
[27]de Luca M A,Maehado T E.Synthesis and characterization of epoxidized styrene-butadiene rubber/silicon dioxide hybrid materials[J].Journal of Applied Polymer Science,2004,92(2):798-803.
[28]Bandyopadhyay A,de Sarkar M,Bhowmick A K.Epoxidised natural rubber/silica hybrid nanocomposites by sol-gel technique:Effect of reactants on the structure and the properties[J].Journal of Materials Science,2005,40(1):53-62.
[29]Kazumasa Yoshikai,Tetsaro Ohsaki.Silica reinforcement of synthetic diene rubbers by sol-gel process in the latex[J].Journal of Applied Polymer Science,2002,85(10):2053-2063.
[30]Miyamoto Yoshiaki,Terakawa Katsumi.Diene rubber compositions with high strength and resilience and exhibiting low energy loss:JP,09176385[P].1997-08-07.
[31]段先健,张立群,伍社毛,等.用溶胶-凝胶法原位生成SiO2增强橡胶[J].合成橡胶工业,2000,23(3):148-152.

收稿日期：2008年4月15日

修稿日期：2009年2月19日

出版日期：2009年5月15日

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