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合成橡胶工业 |
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合成橡胶工业 |
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水性聚氨酯-氯丁二烯杂化胶乳的制备 张雯 袁荞龙 马东柱 郝喜庆 摘 要：在聚氨酯预聚体中加入氯丁二烯和少量甲基丙烯酸甲酯,经相反转分散到水相后聚合,制备了水性聚氨酯-氯丁二烯杂化胶乳,用傅里叶变换红外光谱对其进行了表征.结果表明,水性聚氨酯-氯丁二烯杂化胶乳的外观、粒径和ζ电位说明它是稳定的,杂化后的聚氨酯胶乳粒径增加、ζ电位降低. Preparation of water-borne polyurethane-chloroprene hybrID latex
Zhang Wen（Key Laboratory for Ultrafine Materials of Ministry of Education,School of Materials Science and Engineering,East China University of Science and Technology,Shanghai 200237,China）
Yuan Qiaolong（Key Laboratory for Ultrafine Materials of Ministry of Education,School of Materials Science and Engineering,East China University of Science and Technology,Shanghai 200237,China）
Ma Dongzhu（Shanxi Synthetic Rubber Group Co Ltd,Datong 037005,China）
Hao Xiqing（Shanxi Synthetic Rubber Group Co Ltd,Datong 037005,China）
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Polyurethane(PU), acrylic polymer, polychloroprene, polyester, and polyamIDe have been wIDely used in adhesives and discussed[1]. Development of new environmentally friendly products and technologies has boosted efforts of scientific researchers in new materials. Water-borne PU has already been studied and developed in the field of applications such as adhesives and coatings. Polychloroprene was prepared from chloroprene(CP) via free radical emulsion polymerization[2]. …… |
| 基金项目：Supported by Shanghai Leading Academic Discipline Project(B 502). 作者简介：Zhang Wen,graduate student 张雯（华东理工大学,材料科学与工程学院,教育部超细材料制备与应用重点实验室,上海,200237） 袁荞龙（华东理工大学,材料科学与工程学院,教育部超细材料制备与应用重点实验室,上海,200237） 马东柱（山西合成橡胶集团有限责任公司,山西,大同,037005） 郝喜庆（山西合成橡胶集团有限责任公司,山西,大同,037005） 参考文献：
[1]Manivannan G.Role of polymers as adhesives[J].Popular Plastics & Packaging,1993,38(1):57-60. |
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收稿日期：2009年1月12日 出版日期：2009年7月15日 |
