橡胶技术网

合成橡胶工业
CHINA SYNTHETIC RUBBER INDUSTRY
2009 Vol.32 No.4 P.352-354

 橡胶技术网

桥键烷基酚及其衍生物用于合成橡胶防老剂的研究进展

杜飞　 郭付远　

摘　要：分析了2,6-二叔丁基-4-甲基苯酚(BHT)作为合成橡胶防老剂存在易迁移、易挥发、抗老化效率低等问题,阐述了BHT与桥键烷基酚类防老剂的作用机理,介绍了桥键烷基酚类防老剂的优势、合成方法,指出用桥键烷基酚及其衍生物取代BHT是合成橡胶防老剂发展的方向.
关键词：桥键烷基酚;2,6-二叔丁基-4-甲基苯酚;双酚单丙烯酸酯;合成橡胶;防老剂
分类号：TQ314.24+9 　文献标识码：A
文章编号：1000-1255(2009)04-0352-03

Research progress in antioxIDant of brIDged alkyl phenols category and its derivates used for synthetic rubber

Du Fei （Department of Chemical Engineering,Jiangsu Polytechnic University,Changzhou 213164,China）　 Guo Fuyuan（Department of Chemical Engineering,Jiangsu Polytechnic University,Changzhou 213164,China）　

Abstract：The shortcoming such as easily migration, volatile and low antiaging efficiency of 2,6-di-tert-butyl-4-methylphenol(BHT) as synthetic rubber antioxIDant was analyzed, the mechanism of antiaging of BHT and brIDged alkylene phenols were explained, and the advantage, synthetic methods of brIDged alkylene bisphenols were introduced with 20 references. It was pointed out that brIDged alkylene phenols and its derivates replacing BHT would be the direction of antioxIDant for synthetic rubber.
Keywords：brIDged alkyl phenol; 2,6-di-tert-butyl-4-methylphenol; bisphenolmonoacryate; synthetic rubber; antioxIDant

作者简介：杜飞(1957-),男,教授.已发表论文15篇.
作者单位：杜飞（江苏工业学院,化工系,江苏,常州213164）　
　　　　　郭付远（江苏工业学院,化工系,江苏,常州213164）　

参考文献：

[1]Pospisil J.Mechanistic action of phenolic antioxIDants in polymers:A review[J].Polymer Degradation and Stability,1988,22(3):181-202.
[2]Schopov I,Kassabova N,Kossmehl G.OxIDation of cis-1,4-polybutadiene by singlet oxygen[J].Polymer Degradation and Stability,1989,25(1):31-38.
[3]Rabek J F,Ranby B,Arct J,et al.Stabilization of cis-1,4-polybutadiene against photo-oxIDation and singlet oxygen oxIDation by hindered phenols[J].Polymer Degradation and Stability,1983,5(1):65-77.
[4]Fan J L,James C,Chien W.Thermal degradation studies of segmented thermoplastic elastomers[J].Polymer Degradation and Stability,1985,12(1):43-63.
[5]Knobloch D G,Kanouni D M,Fagouri C.Improved processing stabilizer systems[J].Rubber World,2006,234(5):22-27.
[6]Dopico G M S,Lopze V J M,Gonzaler R M V.AntioxIDant content of and migration from commercial polyethylene,polypropylene,and polyvinyl chlorIDe packages[J].Agric Food Chem,2007,55(8):3225-3231.
[7]Yachigo S,Sasaki M,Takahashi Y,et al.Studies on polymer stabilizers(part Ⅰ):A novel thermal stabilizer for butadiene polymers[J].Polymer Degradation and Stability,1988,22(1):63-77.
[8]张萍,杨清华.抗氧剂2246在BR生产中的应用[J].合成橡胶工业,1994,17(4):207-211.
[9]Morris J.EPA comments on chemical RTK HPV challenge submission:BrIDged alkyl phenols category[R].Arlington:Rubber and Plastic Additives Panel of American Chemistry Council,2007:1-6.
[10]Amorati R,Lucarini M,Mugnaini V,et al.AntioxIDant activity of o-bisphenols:The role of intramolecular hydrogen bonding[J].Journal of Organic Chemical,2003,68(13):5198-5204.
[11]Yachigo S,IDa K,Sasaki M,et al.Studies on polymer stsbilizers(part Ⅴ):Influences of structural factors on oxIDative discoloration and thermal stability of polymers[J].Polymer Degradation and Stability,1993,39(3):317-328.
[12]杜飞.丁二烯类聚合物的抗氧剂的制备方法与用途:中国,200610086145.3.[P].2007-02-12.
[13]陈晓东,赵天宇,刘系尧.抗氧剂2246合成研究[J].精细石油化工,1998,15(4):1-3.
[14]王晓丹,冯婧微,阎峰,等.高位阻双酚2,2′-亚甲基双(4,6-二叔丁基苯酚)的合成[J].当代化工,2005,34(2):117-120.
[15]井上喜久光.双酚类化合物的制备方法:JP,239204[P].2000-09-05.
[16]井上喜久光.双酚类化合物的制备方法:JP,36685[P].2006-02-09.
[17]杜飞,朱睿.2,2′-亚乙基双(4,6-二叔戊基苯酚)的清洁化合成工艺[J].化工进展,2008,27(4):602-605.
[18]杜飞,常美荣,刘军,等.新型抗氧剂XD-1580在顺丁橡胶BR 9000中的应用研究[J].合成橡胶工业,2008,31(6):414-417.
[19]杜飞.双酚单丙烯酸酯类抗氧剂GM的合成[J].精细化工,2006,23(10):1007-1010.
[20]杜飞.一种双酚单丙烯酸酯类抗氧剂的制备方法:中国,200510035209.2[P].2006-12-05.

收稿日期：2008年6月2日

修稿日期：2009年6月5日

出版日期：2009年7月15日

请看PDF全文