橡胶技术网

合成橡胶工业
CHINA SYNTHETIC RUBBER INDUSTRY
2009 Vol.32 No.6 P.522-526

橡胶技术网

纳米二氧化硅的结构及表面改性对橡胶复合材料性能影响的研究进展

许石豪  刘丰  李小红  张治军 

摘 要:分析了纳米SiO_2结构及表面改性对其填充橡胶复合材料性能的影响,对比了不同表面改性方法对SiO_2增强效果的影响,指出基于良好分散性的适度结构化和高效功能化表面改性是提高SiO_2增强橡胶复合材料性能的重要因素.简要介绍了纳米SiO_2在橡胶复合材料中的应用研究现状.
关键词:纳米二氧化硅;结构;表面改性;橡胶纳米复合材料;综述
分类号:TQ330.38~+3  文献标识码:A

文章编号:1000-1255(2009)06-0522-05

Research progress in effect of structure and surface modification of nanosilica on properties of rubber composites

Xu Shihao(Key Laboratory of Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475001, China)  Liu Feng(Key Laboratory of Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475001, China)  Li Xiaohong(Key Laboratory of Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475001, China)  Zhang Zhijun (Key Laboratory of Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475001, China) 

AbstractEffect of structure and surface modification of nanosilica on properties of rubber composites were discussed.Effect of surface treatment methods on enhencement effect of nanosilica were compared with 42 references.It was pointed out that moderate structurization with good dispersion and efficiently functionalized surface modification of nanosilica were very important to properties of the rubber composites.The research status of application of nanosilica in rubber composites were briefly introduced.
Keywords:nanosilica; structure morphology; surface modification; rubber nanocomposite; review

基金项目:国家"九七三"计划资助项目(2007 CB 607606) .
作者简介:许石豪(1980-),男,硕士研究生.已发表论文2篇.
作者单位:许石豪(河南大学,特种功能材料教育部重点实验室,河南,开封,475001) 
     刘丰(河南大学,特种功能材料教育部重点实验室,河南,开封,475001) 
     李小红(河南大学,特种功能材料教育部重点实验室,河南,开封,475001) 
     张治军(河南大学,特种功能材料教育部重点实验室,河南,开封,475001) 

参考文献:

[1]Maclachlan M J,Manners I,Ozin G A.New (inter)faces:Polymers and inorganic materials[J].Adv Mater,2000,12(9):675-681.
[2]Balakrishnan S,Start P R,Raghavan D,et al.The influence of clay and elastomer concentration on the morphology and fracture energy of preformed acrylic rubber dispersed clay filled epoxy nanocomposites[J].Polymer,2005,46(5):11255-11262.
[3]Song Haojie,Zhang Zhaozhu,Men Xuehu.Surface-modified ca-rbon nanotubes and the effect of their addition on the tribological behavior of a polyurethane coating[J].European Polymer Journal,2007,43(10):4092-4102.
[4]Zhang Zhenjun,Zhang Lina,Li Yang,et al.New fabricate of styrene-butadiene rubber/montmorillonite nanocomposites by anionic polymerization[J].Polymer,2005,46(1):129-136.
[5]Luca M A,Machado T E,Notti R B,et al.Synthesis and characterization of epoxidized styrene-butadiene rubber/silicon dioxide hybrid materials[J].J Appl Polym Sci,2004,92:798-803.
[6]Bandyopadhyay A,De Sarkar M,Bhowmick A K.Synthesis and characterization of acrylic rubber/silica hybrid composites prepared by sol-gel technique[J].Rubb Chem Technol,2004,77(5):830-846.
[7]Arrighi V,Mcewen I J,Qian H,et al.The glass transition and interfacial layer in styrene-butadiene rubber containing silica nanofiller[J].Polymer,2003,44(20):6259–6266.
[8]Menon A R R,Pillai C K S,Jin W S,et al.Fatigue resistance of silica-filled natural rubber vulcanizates:Comparative study of the effect of phosphorylated cardanol prepolymer and a silane coupling agent[J].Polymer International,2005,54(4):629-635.
[9]杨清芝.实用橡胶工艺学[M].北京:化学工业出版社,2005:70-71.
[10]Lee J H,Ji W Y.Electrical and mechanical properties of silicone rubber for highvoltage insulation[J].Properties and Applications of Dielectric Materials,2003(2):591-594.
[11]张立群,王振华,吴友平,等.橡胶纳米增强中的逾渗行为及其机理[J].合成橡胶工业,2008,31(4):245-250.
[12]Suzuki N,Ito M,Yatsuyanagi F.Reinforcement effect of MAA on nano-CaCO_3-filled EPDM vulcanizates and possible mechanism[J].Polymer,2005,46:193-201.
[13]Wagner H D,Vaia R A.Nanocomposites:Issues at the interface[J].Materials Today,2004,7(11):38-42.
[14]Ito M,Isago H,Suzuki N.ESR study of silica-filled SBR with different rubber/filler interactions[J].J Appl Polym Sci,2008,108(3):1385-1392.
[15]Friedlander S K,Jang H D,Ryu K H.Elastic behavior of nanoparticle chain aggregates[J].Jounal of Nanoparticle Research,1999,1(1):9-15.
[16]Sun Jin,Song Yihu,Zheng Qiang,et al.Nonlinear rheological behavior of silica filled solution-polymerized styrene butadiene rubber[J].Journal of Polymer Science(part B):Polymer Physics,2007,45(18):2594–2602.
[17]Ramier J,Gauthier C,Chazeau L,et al.Payne effect in silica-filled styrene-butadiene rubber:Influence of surface treatment[J].Polymer Physics,2007,45(3):286-298.
[18]Raos G,Moreno M,Elli S.Computational experiments on filled rubber viscoelasticity:What is the role of particle-particle interactions?[J].Macromolecules,2006,39(19):6744-6751.
[19]Ponomarenko S M,Privalko E G,Privalko V P,et al.Structure and thermoelasticity of synthetic rubber/silica composites[J].Journal of Macromolecular Science(Physics),2004,43(66):1231-1242.
[20]Pu Z C,Mark J E.Effects of dispersion and aggregation of silica in the reinforcement of poly(methyl acrylate) elastomers[J].Chem Mater,1997,9(11):2442-2447.
[21]Wang Mengjiao.Effect of polymer-filler and filler-filler interactions on dynamic properties of filled vulcanizates[J].Rubber Chemistry and Technology,1998,71(3):541-542.
[22]Payne A R,Whittaker R E.Effect of vulcanization on the low-strain dynamic properties of filled rubbers[J].J Appl Polym Sci,1972,16(5):1191-1212.
[23]Zhang Milin,Ding Liguo,Jing Xiaoyan,et al.Preparation,modification and application of nanoscal SiO2[J].Appl Sci Technol,2004,31(6):64-66
[24]Liu Yingling,Hsu Chih-Yuan,Wang Meiling,et al.A novel approach of chemical functionalization on nano-scaled silica particles[J].Nanotechnology,2003,14(7):813-819.
[25]钱燕超.纳米二氧化硅在丁苯橡胶基体中的分散和聚集研究[D].北京:北京化工大学,2006:55-62.
[26]Rangsunvigit P,Imsawatgul P,Na-ranong N,et al.Mixed surfactants for silica surface modification by admicellar polymerization using a continuous stirred tank reactor[J].Chemical Engineering Journal,2008,136(2):288-294.
[27]任慧,屈一新,赵素合,等.硅烷偶联剂改性二氧化硅用于补强丁苯橡胶[J].硅酸盐学报,2006,34(8):951-955.
[28]李瑞隽.封端型巯基硅烷偶联剂的合成及其在白炭黑补强丁苯橡胶中的应用[D].杭州:浙江大学,2007.
[29]周明,宋义虎,孙晋,等.硅烷偶联剂对 SSBR/SiO_2 混炼胶体系动态流变行为的影响[J].高分子学报,2007,(2):153 -157.
[30]Li Xiaohong,Cao Zhi,Liu Feng,et al.A novel method of preparation of superhydrophobic nanosilica in aqueous solution[J].Chemistry Letters,2006,35(1):94-95.
[31]刘丰,郑秋红,李小红,等.可分散性纳米二氧化硅增强硅橡胶[J].复合材料学报,2006,23(6):57-63.
[32]郑秋红,刘丰,李小红,等.可分散性纳米二氧化硅补强硅橡胶的性能[J].高分子材料科学与工程,2007,23(3):139-142.
[33]Xu Xiangmin,Li Bingjie,Lu Huimin,et al.The interface structure of nano-SiO_2/PA 66 composites and its influence on material's mechanical and thermal properties[J].Applied Surface Science,2007,254(5):1456-1462.
[34]Xu Xiangmin,Li Bingjie,Lu Huimin,et al.The effect of the interface structure of different surface-modified nano-SiO_2 on the mechanical properties of nylon 66 composites[J].J Appl Polym Sci,2008,107(3):2007-2014.
[35]刘吉文,许海燕,吴驰飞.环氧天然橡胶接枝高分散白炭黑增强天然橡胶复合材料的制备及表征[J].高分子学报,2008(2):123-128.
[36]Risako Y,Yoko T,Hirofumi K,et al.Preparation of antibacterial polymer-grafted nano-sized silica and surface properties of silicone rubber filled with the silica[J].Polymer Journal,2006,38(8):844-851.
[37]葛奉娟,朱捷.醇酯法表面改性超细二氧化硅的研究[J].安徽理工大学学报:自然科学版,2005,25(4):78-80.
[38]Ossenkamp G C,Kemmitt T,Johnston J H.In situ synthesis of polysulfides covalently bonded to silica[J].Journal of Colloid and Interface Science,2002,249(2):464-470.
[39]Tan H S,Isayev A I.Comparative study of silica-,nanoclay-and carbon black-filled EPDM rubbers[J].J Appl Polym Sci,2008,107(2):767-774.
[40]Eid M A M,El-Nashar D E.Filling effect of silica on electrical and mechanical properties of EPDM/NBR blends[J].Polymer-Plastics Technology and Engineering,2006,45(6):675-684.
[41]Zheng Peng,Ling Xuekong,Li Sidong,et al.Self-assembled natural rubber/silica nanocomposites:Its preparation and characterization[J].Composites Science and Technology,2007,67(15/16):3130-3139.
[42]Cordier P,Tournilhac F,Soulie-Ziakovic C,et al.Self-healing and thermoreversible rubber from supramolecular assembly[J].Nature,2008,451(21 February 2008):977-980.

收稿日期:2008年12月8日

修稿日期:2009年7月20日

出版日期:2009年11月15日