作者简介：吕玉相(1964-),男,吉林德惠人,吉林化学工业股份有限公司有机合成厂橡胶技术分中心主任,工程师,现从事合成橡胶技术开发工作.
作者单位：吕玉相（吉林化学工业股份有限公司有机合成厂,吉林,吉林,132022）
参考文献：
［1］Yu-Ren Chin.Manufacturing techniques for EPDM[J]. European Rubber Journal,1999,181(1):7.
［2］Cozewith charles,Datla.sudhm.Silicate-modified EPDM catalyst system[P].EP:202060,1986.
［3］Tanaglia,Tiziano; Ziegler-Natta catalysts for manufacturing of low crystallinity ethylene copolymer rubber [P].EP:544 340,1993.
［4］Akiyama ,Takashi, Manufacture of synthetic rubber [P].JP:61268707,1986.
［5］Takao Hivoyoshi; Manufacture of heat-and oil-resistant ethylene-propylene-unconjugated polyene copolymer rubber [P].EP:275 925,1988.
［6］Monoi,Hisashi. Preparation of ethylene-α-olefin random copolymers[P].JP:04185618,1992.
［7］Knanf Thomas F. Process for production of ethylene -α-olefin rubbers with reduced fouling [P].EP:652234,1995.
［8］Khan ,Tamil A., Ethylene copolymerization process[J].CA:114:64 004j.
［9］Inoe Tokvji.Preparation of elastomeric olefin copolymers with low vanadium content [P].JP:05 262 826,1993.
［10］Seppala, Jukka Veli; koivumaki. Manufacture of elastomeric, particulate of olefin rubbers[J].CA118:81625n.
［11］Banzi,viviano. Manufacture of ethylene-propylene copolymer elastomers with a high purity and controlled molecular weight distribution [P].EP:731114, 1996.
［12］鲍爱华,世界乙丙橡胶供需趋势与主要技术进展[J]. 合成橡胶工业,1997,20(5):259-263.
［13］Husseiu,Fathi D., Manufacture of sticky polymer in gas-phase ractors[P].US:5194526,1993.
［14］Painter Roger B. Gas-phase fluidized-bed olefin polymerization process using gas -solids tangentting flame [P].US:5 428 118,1995.
［15］Fisinger Ronald S. Producing sticky polymer in a fluidized bed reactor [P].US:5264506,1993.
［16］朱景芬,90年代国内外乙丙橡胶催化剂的研究进展[J].橡胶工业,2000,47(4):206-213.
［17］Floyd Sigmund. Manufacture of elastomers using an indenyl metallocene containing catalyst system [P].WO:9516716,1995.
［18］Schiffino Rinaldo S.. High temperature solution polymerization process using substituted unbridged metallocene catalyst[P].US:5625016,1997.
［19］Mueler P.. High flexible propylene-ethylene copolymers ,their preparation and their use [P].EP:702038,1996.
［20］Gillis Daniel John. Cation-generating cocatalyst for activating a metallocene procatalyst for manufacture of polyolefin elastomer [P].WO:9738019,1997.
［21］mitsui announces EPDM plant[J]. European Rubber Journal 180(10):9,1998.
［22］Job Robert C., Producing ethylene-propylene-diene terpolymer rubbers [P].US:5229477,1993.
［23］Saganl Toshihiro. Unsaturated ethylene polymer rubbers and their manufacture[P]. EP:691354,1996.
［24］Dolatkhani Marc. Linear nonconjugated dienes from biomass as termonomers in EPDM synthesis [J].Macromol Chem.Phys.,197(8):2481-2491.
［25］Kawada Takashi .Unsaturated ethylene-olefin random copolymers and their compositions[P].JP:0251512,1990.
［26］Stephen D.Brignac; Connie smith. New ultra-low Viscosity EP(D)M[J]. Rubber world 21507:49,1996.
［27］David shaw. Uniroyal brings Trilene to Europe[J]. European Rubber, 1996,128(9):28.
［28］Brqi-karre, G.V.; Kisin,K.V..Removal of ziegler-Natta catalyst residues from polyolefin rubber solutions[J].CA118:61339u.
［29］CA118:61 339u.
［30］Inoe Tokuji. Purification of olefin copolymer elastomers for removal of metalcatalysts[P].JP:0665320,1994.
［31］Takeuchi Mikio. Process for producting ethylinic copolymer[P].WO:9019747,1991.
［32］Joyee William H.. Reduction of agglomeration in the production of elastomers[P].US:5086132,1992.
［33］秦卫平,乙丙橡胶生产的技术经济分析[J].现代化工,2000,20(3):38-40.
|
收稿日期：2002年11月26日
出版日期：2003年2月1日
|
