橡胶技术网

弹性体
CHINA ELASTOMERICS
2003 Vol.13 No.6 P.54-60

橡胶技术网

原子转移自由基聚合中过渡金属催化剂的研究进展

Recent advance of transition-metal catalyst system in atom transfer radical polymerization

钟玲  华静  杨卫海  贾彬彬  陈滇宝 

摘 要:综述了正向、反向原子转移自由基聚合(ATRP)中不同种类过渡金属催化剂的特点和进展以及配体对催化剂催化活性和选择性的影响.
关键词:过渡金属;催化剂;ATRP;综述
分类号:TQ314.24  文献标识码:A

文章编号:1005-3174(2003)06-0054-07

基金项目:国家自然科学基金资助项目(No:20074018)
作者简介:钟玲(1974-),女,山东泰安人,青岛科技大学在读硕士研究生.陈滇宝,通讯联系人,E-mail:chendian@public.qd.sd.cn.
作者单位:钟玲(青岛科技大学,高分子科学与工程学院,山东,青岛,266042) 
     华静(青岛科技大学,高分子科学与工程学院,山东,青岛,266042) 
     杨卫海(青岛科技大学,高分子科学与工程学院,山东,青岛,266042) 
     贾彬彬(青岛科技大学,高分子科学与工程学院,山东,青岛,266042) 
     陈滇宝(青岛科技大学,高分子科学与工程学院,山东,青岛,266042) 

参考文献:

[1]Wang J. S.,Matyjaszewski K..Controlled "Living"Radical Polymerizaton Atom Transfer Radical Polymerization in the Presence of Transition-Metal Complexes[J].J. Am. Chem. Soc.,1995,117(20):5614-5619.
[2]Brandts,J.A.M.,vande.Geijn P.,van.Faassen,E.E.,Boersma,J.,van Koten,G.J.Organomet.Chem..1999,584,246.
[3]Francois,S.,Jerome,C.,Rinaldo,P.C.R.Atom transfer radical polymerization of styrene controlled by phosphine-containing coordination compounds of Mo(Ⅲ)/Mo(Ⅱ)[J].Chimie,2002,5:37-42.
[4]Zhong Ling,Hua Jing,Chen Dianbao.Atom transfer radical polymerization of butadiene initiated by benzyl chloride(phCH2Cl)/MoCl3(OC8H17)2/PPh3.合成橡胶工业(待发).
[5]Kotani,Y.,Kamigaito,M.,Sawamoto,M.Re(Ⅴ)-Mediated Living Radical Polymerization of Styrene:ReO2I(PPh3)/R-I Initiating Systems[J].Macromolecules,1999,32:2420.
[6]Kato,M.,Kamigaito,M.,Sawamoto,M.,Higashimura T..Polymerization of Methyl Methacrylate with the Carbon Tetrachloride\pichlorotris.(triphenylphosphine)ruthenium(Ⅱ).Methlaluminum Bis(2,6-di-tert -butylphen oxide)Initiating System:Possibility of Living Radical Polymerezation[J].Macromolecules,1995,28:1721.
[7]Akahashi,H.,Ando,T.,Kamigaito,M.,Sawamoto,M.Half-Metallocence-Type Ruthenium Complexes as Active Catalysts for Living Radical Polymerization of Methyl Methacrylate and styrene[J].Macromolecules,1999,32:3820.
[8]Ando,T.,Kamigaito,M.,Sawamotok,M..Catalytic activities of ruthenium(Ⅱ)complexes in transition-metal-mediated living radical polymerization,model reaction and cyclic voltammetry[J].Macromolecules 2000,33:5825.
[9]Bielawski,C.W.,Louie,J.,Grubbs,R.H.Tandem Catalysis:Three Mechanistically Distinct Reactions from a Single Ruthenium Complex[J].J.Am.Chem.Soc.,2000,122:12872.
[10]Bob DC,Francis V.A new class of ruthenium complexes containing Schiff base ligands as promising catalysts for atom tuansfer radical polymerization and ring opening metathesis polymerization[J].Journal of Molecular Catalysis A:Chemical,2002,180:67-76.
[11]Ando,T.,Kamigaito,M.,Sawamoto,M.Iron(Ⅱ)Chloride Complex for Living Radical Polymerization of Methacrylate[J].Macromolecules,1997,30:4507.
[12]Matyjaszewski,K.,Wei,M.,Xia,J.,McDermott,N,E.Controlled "Living"Radical Polymerization of Styrene and Methyl Methacrylate Catalyzed by Iron Complexes[J].Macromolecules,1997,30:8161.
[13]Kotani,Y,Kamigaito,M,Sawamoto,M.FeCp(CO)2I:Aphosphine-Free Half-Metallocene-Type Iron(Ⅱ)Catalyst for Living Radical Polymerization of Styrene[J].Macromolecules,1999,32:6877.
[14]Teodorescu,M,Gaynor,S.G.,Matyjaszewski,K.Halide Anions as Ligands in Iron-Mediated Atom Transfer Radical Polymerization[J].Macromlecules,2000,33:2335.
[15]Louie,J.,Grubbs,R.H.Highly active iron imidazolylidene catalysts for atom transfer radical polymerization[J].Chem.Commun.2000,1497.
[16]Moineau,G.,Dubois,P.,Jerome,R.,Senninger,T.,Teyssie,P..Alternative Atom Transfer Radical Polymerization for MMA Using Fecl 3 and AIBN in the presence of Triphenylphosphine:An Easy Way to Well-Controlled PMMA[J].Macromolecules 1998,31:545.
[17]Qin DQ,Qin SH,Qiu KY.Reverse atom transfer radical polymerization of vinyl monomers with Fe[SC(S)NEt2]3 alone as the catalyst[J].J Polym Sci Part A:Polym Chem 2001,39:3464-3473.
[18]Percer,V.,Barboiu,B.,Neumann,A.,Ronda metal-catalyzed "Living"radical polymerization of styrene initiated with arenesulforyl chlorides.from heterogeneous to homogeneous catalysis[J].Macromolecules,1996,29:3665.
[19]Uegaki.H.,Kamigation.M.,Sawamoto M..The living radical polymerization of methacrylate with a zero valent Nickel Comples,Ni(pph3)4[J].J.Polym. Sci.Poly.Chem.,1993,37:3003-3009.
[20]Moineau,G,,Minet,M.,Dubois,P.,Teyssie,P.,Senninger,T.,Jerome,R.controlled radical polymeri-zation of(meth)acrylates by ATRP with Nibr2(pph3)2 as catalyst[J].Macromolecules,1999,32:27.
[21]秦乐奇,钦曙辉,丘坤元.镍体系(NiCl2/PPh3)催化的反向原子转移聚合[J].高分子学报,2002,2(1):108.
[22]华静,陈滇宝,贾彬彬,徐玲,周丽玲,于广水.CCl4/Ni(naph)2/P(Ph)3和AIBN/ Ni(naph)2/P(Ph)3催化体系引发苯乙烯的ATRP聚合初探[A].2002全国高分子材料工程应用研讨会论文集[C].2002,67-69.
[23]Lecomte,P.,Drapter,I.,Dubois,P.,Jerome,R.Controlled radical polymerization of methyl methacrylate in the presence of palladium acetate,triphenylphosphine,and carbon tetrachloride[J].Macromolecules,1997,30:7631.
[24]Filiberto G.G,Mauricio R.P,Bluma G.S.Grafting of polymethyl methacrylate from poly(ethylene-co vinylacetate)copolymer using atom tranfer radical polymerization[J].European Polymer Journal 2000,38:759-769.
[25]Ranganathan K, Kalathur SVS.Controlled "living" atrom transfer radical polymerization of methyl methacrylate in the synthesis of triblock copolymers from a poly(oxyethylene) macroinitiator[J].European Polymer Journal,2003,39:205-210.
[26]Xia J,Matyjaszewski,K.. Controlled "Living" radical polymerization.atom transfer radical polymerization catalyzed by copper(I) and picolylamine complexes[J].Macromolecules,1999,32:2434.
[27]Li Peng, Qiu KunYuan.Cuprous N,N-diethylditiocarbamate catalyzed reverse atom transfer radical polymerization of methyl methacrylate[J].Polym.Prep. Am.Chem.Soc. Div.,Polymer Chemistry,2002,43(2).
[28]Wang JS,Matyjaszewski K."Living"/controlled radical polymerization.Traansition-metal-catalyzed atom transfer radical polymerization in the presence of a conventional radical initiator[J].Macromolecules,1995,28:7572.
[29]Wang WX,Dong ZH,Xia P,Yan DY,Zhang Q.Reverse atom transfer radical polymerization of methyl acrylate using AIBN as the initiator under heterogeneous conditions[J].Macromol Rapid Commun,1998,19:647.
[30]Xia JH,Matyjaszewski K.Homogeneous reverse atom transfer radical polymerization of styrene initiated by peroxides[J].Macromolecules,1999,32:5199-5202.
[31]Qin DQ,Qin SH,Qiu KY.Living/controlled radical polymerization of styrene with a new initiating system:DCDEPS/FeCl3/PPh3[J].J.Polym.Sci.Part A:Polym.Chem.,2000.
[32]Qin DQ,Qin SH,Qiu KY.A reverse ATRP process with a hexasubstituted ethane thermal iniferter diethyl 2,3-dicyano-2,3-di(p-tolyl)succinate as the initiator[J].Macromolecules,2000,33:6987-6992.


收稿日期:2003年7月24日

出版日期:2003年12月1日

请看PDF全文