橡胶技术网

弹性体
CHINA ELASTOMERICS
2004 Vol.14 No.4 P.57-61

橡胶技术网

超支化大分子的最新应用进展

Advance on application of hyperbranched polymer

万涛  王跃川 

摘 要:超支化大分子独特的构筑使其合成与应用在世界范围内受到人们越来越多的关注.笔者对最近以来国内外超支化大分子的最新应用进行了简要的综述,对今后超支化大分子的应用前景进行了展望和预测.
关键词:超支化大分子;嵌段共聚物;螯合;端基
分类号:TQ316.6+1 文献标识码:A

文章编号:1005-3174(2004)04-0057-05

作者简介:万涛(1967-)男,四川泸州人,讲师,任教于成都理工大学材料与生物工程学院,现四川大学高分子材料工程与科学学院在职博士,主要研究领域涉及涂料、絮凝剂、高吸水树脂、插层纳米复合材料和超支化大分子的合成与应用,联系电话:028-85401816.
作者单位:万涛(成都理工大学,材料与生物工程学院,四川,成都,610059;四川大学,高分子材料国家重点实验室,四川大学,高分子材料与工程学院,四川,成都,610061) 
     王跃川(四川大学,高分子材料国家重点实验室,四川大学,高分子材料与工程学院,四川,成都,610061) 

参考文献:

[1]A. Lederer, D. Voigt, C. Clausnitzer, B. Voit. Structure characterization of hyperbranched poly(ether amide)s-1. Preparative fractionation[J]. Chromatography, Part A, 2002,976, 171~179.
[2]D.Schmaljohann, H. Komber, J. Barratt, D. et al. Kinetics on Non-ideal hyperbranched polymerizations[J].Macromolecules ,2003,36, 97~108.
[3]B. Voit, D. Beyerlein K.J. Eichhorn, K. Et al. Functional hyperbranched polyesters for application in blends[J]. Coating, and Thin Films,Chem.E ng.Technol,2002, 25, 704~707.
[4]Tabuani, D.,Monticelli, O.,Chincarini, A.,et al.Palladium nanoparticles supported on hyperbranched aramids: synthesis, characterization, and some applications in the hydrogenation of unsaturated substrates[J]. Macromolecules,2004; 37(2): 680~680.
[5]WeberskirchR,Hettich R,et al..Synthesis of new amphiphilic star polymers derived from a hyperbranched macroinitiator by the cationic "grafting from" method[J].Macromol Chem.Phys.,1999,200,863~873.
[6]Iyer J,Fleming k,etc.Synthesis and solution properties of new linear-dendritic diblock copolymers[J].Macromolecules, 1998,(31):8 757~8 7 65.
[7]Mezzenga R,Boogh L,et al. A review of dendritic hyperbranched polymer as modifiers in epoxy composites[J].Composites Science and Technology,20 01,61:787~795.
[8]Hong Y, Cooper-White JJ, Mackay ME, et al.. A novel processing aid for polymer extrusion: Rheology and processing of polyethylene and hyperbranched polymer blends[J]. Rehnberg N.Journal Of Rheology,1999,43(3):781~793.
[9]J. Karger-Kocsis, J. Frihlich, O. Gryshchuk,etal.. Synthesis of reactive hyperbranched and star-like polyethers and their use for toughening of vinylester-urethane hybrid resins[J].Polymer,2004, 45:1 185.
[10]Hewen Liu , Carl-Eric Wilén, Hyperbranched polymers with maleic functional groups as radical crosslinkers[J].J.Polym.Sci.A.Polym.Chem.,2 001,39: 964~972.
[11]Daoji Gan, Anja Mueller, Karen L. Wooley. Amphiphilic and hydrophob ic surface patterns generated from hyperbranched fluoropolymer/linear polymer networks: Minimally adhesive coatings via the crosslinking of hyperbranched fluoropolymers, [J].J.Polym.Sci.Part A:Polym.Chem.,2003,41:3 531~3 540.
[12]Klee J E,Schneider,C,etc.. Hyperbranched polyesters and their app lication in dental composites: monomers for low shrinking composites[J].Polymers for advanced technologies,2001,12(4):346~354.
[13]Wan QC,Schricker SR,Culbertson BM.Methacryloyl derivitized hyperbran chen polyester. 2. photo-polymerization and properties for dental resin system s[J].Journal of macromolecular science.Pure and Applied Chemistry,2000,37( 11):1 317~1 331.
[14]Johansson M,Malmstrom E,Jansson A. A novel concept for low temperature curing powder coatings based on hyperbranched polyesters[J].J. Coatings Tech.,2000,72,906.
[15]Zhang Y D,Wada T,etc. A new hyperbranched polymer with polar chromophores for nonlinear optics[J].Polymer,1997,38(12):2 893~2 897.
[16]Zhang L, Wang T, Wada H. Sasabe. One-pot synthesis of a new hyperbranched polyester containing 3,6-di-acceptor-substituted carbazole chromophores for nonlinear optics[J].Macromol Chem. Phys.,1996,(197):667~676.
[17]Kou H G, Anila A,Shi W F. Photopolymerizable acrylated hyperbranched polyisophthalesters used for photorefractive materials: I. Synthesis and characterization[J].European Polymer Journal,2002,38(10):1 931~1 936.
[18]Bayoudh S, Laschewsky A, Wischerhoff E. Amphiphilic hyperbranched polyelectrolytes: a new type of polysoap[J].Colloid and Polymer Science,1999 ,277(6):519~527.
[19]Wang ZX, Ikeda M, Hirata N, Kubo M, Itoh T. Yamamoto O. Thermal, electrochemical, and spectroscopic characterizations of hyperbranched polymer elect rolyte[J].Journal of The Electrochemical Society,1999,14 696:2 209~2 215.
[20]Bayoudh S, Laschewsky A,etc.Amphiphilic hyperbranched polyelectrolytes: a new type of polysoap[J].Colloid Polym Sci,1999,277:519~527.
[21]Takahito I, Yoshiaki I.et al.. Effect of branching in base polymer on ionic conductivity in hyperbranched polymer electrolytes[J].Solid State Ionics,2002,150(3~4):337~345.
[22]Wen Z Y, et al.Blend-based polymer electrolytes of poly(ethylene oxide) and hyperbranched poly[bis(triethylene glycol)benzoate] with terminal acetyl groups[J].Solid State Ionics,2000,134, 281.
[23]Duan L, Qiu Y.Qing G H,etc. A novel hyperbranched conjugated polymer for electroluminescence application[J].Synthetic Metals,2001,124(2~3): 3 73~377.
[24]Tao X.T., Suzuki H., Wada, T., Sasabe, H., Miyata S.Lithium tetra-(8-hydroxy-quinolinato) boron for blue electroluminescent applications[J].Applied Physics Letters,1999,75:1 655~1 657.
[25]Zhu S W, Shi W F. Flame retardant mechanism of hyperbranched polyurethane acrylates used for UV curable flame retardant coatings[J].Polymer Degradation and Stability,2002,75(3): 543~547.
[26]Liu, H., Jiang, A., Guo, J., Uhrich, K.E.. Unimolecular micelles: Synthesis and characterization of amphiphilic polymer systems[J].Journal of Polymer Science,Part A: Polymer Chemistry, 1999, 37(6): 703~711.


收稿日期:2003年3月6日

出版日期:2004年8月25日