橡胶技术网

橡胶工业
Xiangjiao Gongye China Rubber Industry
2000 Vol.47 No.8 P.451-455

橡胶技术网

HPVC/SBR共混体系相容性的研究

廖明义  Shershnev V A 

摘 要:采用动态硫化方法制备高聚合度聚氯乙烯(HPVC)/SBR共混型热塑性弹性体,考察了单一组分相容剂[相容剂分别为NBR270、NBRP65、CPE和氢化苯乙烯-丁二烯-苯乙烯嵌段共聚物(SEBS)]、复合相容剂(SEBS/NBR和CPE/NBR)及交联程度对HPVC/SBR共混体系相容性的影响。结果表明,使用复合相容剂可明显改善HPVC/SBR共混物的性能;动态硫化在改善共混物力学性能方面起主要作用。
关键词:高聚合度聚氯乙烯;SBR;动态硫化;相容剂
分类号:TQ330.1+3 文献标识码:A

文章编号:1000-890X(2000)08-0451-05

Study on compatibility of HPVC/SBR blend

LIAO Ming-yi1
(Dalian University of Technology,Dalian 11601)
Shershnev V A
(China;2.Moscow Institute of Fine Chemical Technology,Moscow,Russia)

AbstractA HPVC/SBR blended TPE was prepared by dynamic vulcanization.The effect of the Single compatibilizer(NBR270,NBR P65,CPE and SEBS),the binary compatibilizers(SEBS/NBR and CPE/NBR)and the crosslink density on the compatibility of HPVC/SBR blend was investigated.The results showed that the mechanical properties were significantly improved by adding binary compatibilizer;and the dynamic vulcanization played an important role in improving the mechanical properties of the blend.
Keywords:HPVC; SBR; dynamic vulcanization; compatibilizer

基金项目:辽宁省国际合作资助项目(97704027)
作者简介:廖明义(1962-),男,辽宁大连人,大连理工大学副教授,博士,主要从事聚合物共混方面的研究。
作者单位:廖明义(大连理工大学 化工学院,辽宁 大连 116012) 
     Shershnev V A(2.Moscow Institute of Fine Chemical Technology,Moscow,Russia) 

参考文献:

[1]陈明凤.PVC/橡胶共混硫化物[J].合成树脂及塑料,1988(4):41-46.
[2]张隐西,张 勇.PVC/BR或SBR共混体系的研制[J].高分子材料科学与工程,1989,5(1):66-73.
[3]沙世清,张 涛,谢忠麟.动态硫化PVC/SBR共混型热塑性弹性体的研究[J].橡胶工业,1993,40(5):297-330.
[4]廖明义,舒文淼,李建丰,等.动态硫化HPVC/SBR 共混体系力学性能的研究[J].橡胶工业,1999,46(5):259-262.
[5]廖明义,Shershnev V A.有机过氧化物动态硫化HPVC/SBR共混体系力学性能的研究[J].橡胶工业,1999,46(8):461-463.
[6]廖明义.共聚物相容作用的预测和初步验证[J].橡胶工业,1997,44(9):515-520.

收稿日期:2000-02-14

请看PDF全文