橡胶技术网

橡胶工业
China Rubber Industry
2000 Vol.47 No.11 P.643-646

橡胶技术网

木质素粉末化改性及其在BIIR中的应用

杨军  王迪珍  罗东山 

摘 要:研究了丙酮改性对木质素粉末化工艺及BIIR补强效果的影响。试验结果表明,丙酮改性可降低湿态羟甲基化木质素体系的枯度,并可显著减小干态羟甲基化木质素聚集体的粒径,提高其粉末化程度,但对木质素的回收率影响很小。干态改性木质素的粉末化程度是影响硫化胶各项力学性能的重要因素,丙酮改性可使羟甲基化木质素对硫化胶的补强作用显著增强。
关键词:木质素;粉末化改性;BIIR;丙酮;补强作用
分类号:TQ330.38+3;TQ333.6 文献标识码:B

文章编号:1000-890X(2000)11-0643-04

Application of modified lignin powder to BIIR

YANG Jun ,WANG Di-zhen ,LUO Dongshan
(South China University of Technology,Guangzhou 510640,China)

AbstractThe effect of the lignin powder modified by acetone on the reinforcement to BIIR was investigated.The test results showed that the viscosity of hydroxymethylated lignin water suspension was significantly decreased,the aggregate size of dry hydroxymethylated lignin was remarkably reduced promoting the powdering process of lignin and the recovery was decreased very little by modifying the lignin with acetone.It was found through the comparison for physical properties of the vulcanizates that the reinforcement of hydroxymethylated lignin was significantly increased by the modification with acetone.
Keywords:lignin;BIIR;acetone;reinforcement;modification

基金项目:国家自然科学基金资助项目(59273113)
作者简介:杨军(1972-),男,山东济南人,华南理工大学高分子成型加工专业在读博士生。
作者单位:杨军(华南理工大学 材料科学与工程学院,广东 广州 510640) 
     王迪珍(华南理工大学 材料科学与工程学院,广东 广州 510640) 
     罗东山(华南理工大学 材料科学与工程学院,广东 广州 510640) 

参考文献:

[1]王晓光,王迪珍,吴向东,等.丁腈橡胶/木素树脂硫化胶的微观结构与性能[J].橡胶工业,1989,36(4):193.197。
[2]Kumaran M G,De S K.Utilization of lignin in rubber compounding[J].Journal of Applied Polymer Science,1978,22(8):1 885-1 893.
[3]李延.甘蔗渣硫酸盐木质素与丙烯酰胺接枝共聚的研究[D].广州:华南理工大学,1986.
[4]Kumarsn M G,De S K.Effect of lignin on the physioo-mechenical properties of gum and filled rubbers[J].Polymer,1978,19(4):461-469.

收稿日期:2000-06-03

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